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21.
A complete Barrovian sequence ranging from unmetamorphosed shales to sillimanite–K-feldspar zone metapelitic gneisses crops out in a region extending from the Hudson River in south-eastern New York state, USA, to the high-grade core of the Taconic range in western Connecticut. NNE-trending subparallel biotite, garnet, staurolite, kyanite, sillimanite and sillimanite–K-feldspar isograds have been identified, although the assignment of Barrovian zones in the high-grade rocks is complicated by the appearance of fibrolitic sillimanite at the kyanite isograd. Thermobarometric results and reaction textures are used to characterize the metamorphic history of the sequence. Pressure–temperature estimates indicate maximum metamorphic conditions of 475 °C, c. 3–4 kbar in the garnet zone to >720 °C, c. 5–6 kbar in the highest grade rocks exposed. Some samples in the kyanite zone record anomalous (low) peak conditions because garnet composition has been modified by fluid-assisted reactions. There is abundant petrographic and mineral chemical information indicating that the sequence (with the possible exception of the granulite facies zone) was infiltrated by a water-rich fluid after garnet growth was nearly completed. The truncation of fluid inclusion trails in garnet by rim growth or recrystallization, however, indicates that metamorphic reactions involving garnet continued subsequent to initial infiltration. The presence of these textures in some zones of a well-constrained Barrovian sequence allows determination of the timing of fluid infiltration relative to the P–T paths. Thermobarometric results obtained using garnet compositions at the boundary between fluid–inclusion-rich and inclusion-free regions of the garnet are interpreted to represent peak metamorphic conditions, whereas rim compositions record slightly lower pressures and temperatures. Assuming that garnet grew during a single metamorphic event, infiltration must have occurred at or slightly after the peak of metamorphism, i.e. 4–5 kbar and a temperature of c. 525–550 °C for staurolite and kyanite zone rocks.  相似文献   
22.
We report new δ13C ‐values data and N‐content and N‐aggregation state values for microdiamonds recovered from peridotites and chromitites of the Luobusa ophiolite (Tibet) and chromitites of the Ray‐Iz ophiolite in the Polar Urals (Russia). All analyzed microdiamonds contain significant nitrogen contents (from 108 up to 589 ± 20% atomic ppm) with a consistently low aggregation state, show identical IR spectra dominated by strong absorption between 1130 cm?1 and 1344 cm?1, and hence characterize Type Ib diamond. Microdiamonds from the Luobusa peridotites have δ13C ‐PDB‐values ranging from ‐28.7‰ to ‐16.9‰, and N‐contents from 151 to 589 atomic ppm. The δ13C and N‐content values for diamonds from the Luobusa chromitites are ‐29‰ to ‐15.5‰ and 152 to 428 atomic ppm, respectively. Microdiamonds from the Ray‐Iz chromitites show values varying from ‐27.6 ‰ to ‐21.6 ‰ in δ13C and from 108 to 499 atomic ppm in N. The carbon isotopes values bear similar features with previously analyzed metamorphic diamonds from other worldwide localities, but the samples are characterized by lower N‐contents. In every respect, they are different from diamonds occurring in kimberlites and impact craters. Our samples also differ from the few synthetic diamonds; we also analyzed showing enhanced δ13C ‐variability and less advanced aggregation state than synthetic diamonds. Our newly obtained N‐aggregation state and N‐content data are consistent with diamond formation over a narrow and rather cold temperature range (i.e. <950°C), and in a short residence time (i.e. within several million years) at high temperatures in the deep mantle.  相似文献   
23.
Various combinations of diamond, moissanite, zircon, corundum, rutile and titanitehave been recovered from the Bulqiza chromitites. More than 10 grains of diamond have been recovered, most of which are pale yellow to reddish–orange to colorless. The grains are all 100–300 μm in size and mostly anhedral, but with a range of morphologies including elongated, octahedral and subhedral varieties. Their identification was confirmed by a characteristic shift in the Raman spectra between 1325 cm~(-1) and 1333 cm~(-1), mostly at 1331.51 cm~(-1) or 1326.96 cm~(-1). This investigation extends the occurrence of diamond and moissanite to the Bulqiza chromitites in the Eastern Mirdita Ophiolite. Integration of the mineralogical, petrological and geochemical data of the Bulqiza chromitites suggests their multi–stage formation. Magnesiochromite grains and perhaps small bodies of chromitite formed at various depths in the upper mantle, and encapsulated the ultra–high pressure, highly reduced and crustal minerals. Some oceanic crustal slabs containing the magnesiochromite and their inclusion were later trapped in suprasubduction zones, where they were modified by tholeiitic and boninitic arc magmas, thus changing the magnesiochromite compositions and depositing chromitite ores in melt channels.  相似文献   
24.
The Pozanti-Karsanti ophiolite(PKO)in Turkey’s eastern Tauride belt comprises mantle peridotites,ultramafic to mafic cumulates,isotropic gabbros,sheeted dikes and pillow lavas.The mantle peridotites are dominated by spinel harzburgites with minor dunites.The harzburgites and dunites have quite depleted mineral and whole-rock chemical composition,suggesting high degrees of partial melting.Their PGEs vary from Pd-depleted to distinct Pd-enriched patterns,implying the crystallization of interstitial sulphides from sulphur-saturated melts(e.g.MORB-like forearc basalt).U-shaped or spoon-shaped REE patterns indicate that the PKO peridotites may have also been metasomatized by the LREE-enriched fluids released from a subducting slab in a suprasubduction zone.Based on the mineral and whole-rock chemical compositions,the PKO peridotites show affinities to forearc peridotites.Chromitites occur both in the mantle peridotites and the mantle-crust transition zone horizon(MTZ).Chromitites from the two different horizons have different textures but similar mineral compositions,consistent with typical high-Cr chromitites.Chromitites hosted by mantle harzburgites generally have higher total platinum-group element(PGE)contents than those of the MTZ chromitites.However,both chromitites show similar chondritenormalized PGE patterns characterized by clear IPGEs,Rh-enrichments relative to Pt and Pd.Such PGE patterns indicate no or only minor crystallization of Pt-and Pd enriched sulphides during formation of chromitites from a sulphur-undersaturated melt(e.g.boninitic or island arc tholeiitic melt).Dunite enveloping chromitite lenses in the ho*s ting harzburgite resulted from melt-rock reaction.We have performed mineral separation work on samples of podiform chromitite hosted by harzburgites.So far,more than200 grains of microdiamond and more than 100 grains of moissanite(Si C)have been separated from podiform chromitites.These minerals have been identified by EDX and Laser Raman analyses.The diamonds and moissanite are accompanied by large amounts of rutile.Additionally,zircon,monazite and sulphides are also common phases within the heavy mineral separates.Both diamond and moissanite have been analyzed for carbon and nitrogen isotopic composition using the CARMECA 1280-HR large geometry Secondary Ion Mass Spectrometer at the Helmholtz Zentrum Potsdam.In total,61δ13CPDB results for diamond were acquired,exhibiting a range from-28.4‰to-18.8‰.31δ13CPDB results for Moissanite vary between-30.5‰to-27.2‰,with a mean value of-29.0‰.Diamond has relatively large variation in nitrogen isotopic composition with 40δ15NAIR results ranging from-19.1‰to 16.6‰.The discovery of diamond,moissanite and the other unusual minerals from podiform chromitite of the Pozanti-Karsanti ophiolite provides new support for the genesis of ophiolitic peridotites and chromitites under high-pressure and ultra-high reducing conditions.Considering the unusual minerals,the high Mg#silicate inclusions,and the needle-shaped exsolutions in the PKO chromitites,the parental melts of these chromitites may have been mixed with deep asthenospheric basaltic melts that had assimilated materials of the descending slab when passing through the slab in a subduction zone environment.We suggest melt-rock reactions,magma mixing and assimilation may have triggered the oversaturation of chromites and the formation of PKO chromitites.  相似文献   
25.
26.
<正>The IGCP 649 project entitled "Diamonds and Recycled Mantle"was approved by UNESCO and IUGS in March 2015.This project is led by an international team of researchers,including Prof.Yang Jingsui of Institute of Geology of CAGS(China),Prof.Yildirim Dilek of Miami  相似文献   
27.
<正>The internal structure-stratigraphy and geochemical signatures of most forearc-suprasubduction zone ophiolites display structural,petrological,geochemical and geochronological evidence,recording different stages of subduction initiation-related magmatism,material flux,metasomatism and deformation.There is a well-developed  相似文献   
28.
<正>The ultramafic massif of Bulqiza,which belongs to the eastern ophiolitic belt of Albania,is a major source of metallurgical chromitite ore.The massif consists of a thick(4 km)sequence,composed from the base upward of tectonized harzburgite with minor dunite,a transitional zone of dunite,and a magmatic sequence of wehrlite,  相似文献   
29.
The ophiolites that crop out discontinuously along the~2000 km Yarlung Zangbo Suture zone(YZSZ)between the Nanga Parbat and Namche Barwa syntaxes in southern Tibet represent the remnants of Neotethyan oceanic lithosphere(Fig.1a).We have investigated the internal structure and the geochemical makeup of mafic-ultramafic rock assemblages that are exposed in the westernmost segment of the YZSZ where the suture zone architecture displays two distinct sub-belts of ophiolitic and mélange units separated by a continental Zhongba terrane(Fig.1b).These two sub-belts include the Daba–Xiugugabu in the south(Southern sub-belt,SSB)and the Dajiweng–Saga in the north(Northern sub-belt,NSB).We present new structural,geochemical,geochronological data from upper mantle peridotites and mafic dike intrusions occurring in these two sub-belts and discuss their tectonomagmatic origin.In-situ analysis of zircon grains obtained from mafic dikes within the Baer,Cuobuzha and Jianabeng massifs in the NSB,and within the Dongbo,Purang,Xiugugabu,Zhaga and Zhongba in the SSB have yielded crystallization ages ranging between130 and 122 Ma.Dike rocks in both sub-belts show N-MORB REE patterns and negative Nb,Ta and Ti anomalies,reminiscent of those documented from SSZ ophiolites.*Harzburgitic host rocks of the mafic dike intrusionsmainly display geochemical compositions of abyssal peridotites(Fig.2),with the exception of the Dajiweng harzburgites,which show the geochemical signatures of forearc peridotites(Lian et al.,2016).Extrusive rocks that are spatially associated with these peridotite massifs in both sub-belts also have varying compositional and geochemical features.Tithonian to Valanginian(150–135 Ma)basaltic rocks in the Dongbo massif have OIB-like geochemistry and 138 Ma basaltic lavas in the Purang massif have EMORB-like geochemistry(Liu et al.,2015).Tuffaceous rocks in the Dajiweng massif are140 Ma in age and show OIB-like geochemistry.We interpret these age and geochemical data to reflect a rifted continental margin origin of the extrusive rock units in both sub-belts.These data and structural observations show that the western Yarluang Zangbo ophiolites represent fragments of an Ocean-Continent Transition(OCT)peridotites altered by fluids in an initial supersubduction setting.We infer that mafic-ultramafic rock assemblages exposed in the SSB and NSB initially formed in an ocean–continent transition zone(OCTZ)during the late Jurassic,and that they were subsequently emplaced in the forearc setting of an intraoceanic subduction zone within a Neotethyan seaway during 130 to 122 Ma.The NSB and SSB are hence part of a single,S-directed nappe sheet derived from a Neotethyan seaway located north of the Zhongba terrane.  相似文献   
30.
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